Journal of Advanced Chemical Engineering

Department of Chemistry, Teerthankar Mahaveer University, Moradabad, India

Biography

Dr. Anil Kumar Singh is an Associate Professor in the Department of Chemistry at Teerthanker Mahaveer University (TMU), Moradabad, India. He earned his Ph.D. in Physical Chemistry from MJP Rohilkhand University, Bareilly, in 2009. His research focuses on physical and inorganic chemistry, particularly in the areas of chemical reaction kinetics and thermodynamics.

Publications

• Research Article   
  Kinetics of Bimolecular Reaction on Activation Parameters for the Solvolysis of Diethyl Phthalate in Aqueous Alkaline Medium of Ethanol
  Author(s): Anil Kumar Singh*
  
  The kinetics parameters like rate constant, iso-composition activation energy, dielectric activation energy, enthalpy of activation, entropy of activation and Gibb’s free energy of activation for the alkali catalyzed hydrolysis of diethyl phthalate ester have been determined at different range of composition for mixture of water and organic solvent at different range of temperature. The effect of solvent on rate of reaction has been studied on term of salvation and desolvation concepts. The number of water molecule associated with activated complex has been found to be decreases with increase of temperature from 200°C to 400°C, this indicate the mechanistic path followed by the reaction change from unimolecular to bimolecular. The variation of ΔG*, ΔH*, ΔS* with solvent composition and the specific effect of water on the reaction ra.. View more»
  

  DOI: 10.35248/2090-4568.22.12.236

  Abstract HTML PDF

Other relevant publications from this author

• 1. Co-Solvent effect and Kinetics of Alkaline Hydrolysis of Butyle Salicylate

  2. Study of Aqueous Solvent effect and Kinetics in Hydrolysis of Butyle Salicylate in Alkaline Medium of Water and DMF

  3. Kinetics and Reaction Mechanism of Acid-Catalyzed Hydrolysis of Propyl Methanoate in Aqueous Solvent of Propanol-2 and Its Effect on Activation Parameters

  4. Mechanism and solvent kinetics of acid catalysed Hydrolysis of Propyl Methanoate in Binary-Solvent system of water and Propanol-2.