Naoto Yoshida
Department of Biochemistry and Applied Biosciences, University of Miyazaki, 1-1 Gakuen Kibanadai-Nishi, Miyazaki,
Japan
Research Article
Effect of Doping with Metals, Silicate, And Phosphate Ions on Fluorescence Properties and Morphology of Calcite Single Crystals Synthesized in Geobacillus thermoglucosidasius Parent Colonies
Author(s): Rie Murai and Naoto Yoshida
Rie Murai and Naoto Yoshida
Geobacillus thermoglucosidasius cells grown on nutrient agar medium (parent colony) were placed on the surface of a calcite-promoting hydrogel containing acetate and calcium. After incubation at 60°C for 4 days, calcite single crystals of 110-130 μm in diameter were synthesized within the parent colony. The calcite contained 6.6% (atom%) Mg and showed striking fluorescent properties. Changes in the morphology and development of fluorescence intensity of calcite synthesized on calcite-promoting hydrogel doped with different metal ions, silicate ion, and phosphate ion were investigated. Doping with Mg, P, or Sr ions yielded calcite lattices with the respective metal ions substitutionally dissolved into calcium sites. On calcite-promoting hydrogel containing 2 mM Mg ion, the calcite Mg content increased to 22 atom%. Doping of the hydrogel with Al, Si, or P ions yielded calcites wi.. View More»
DOI:
10.4172/1948-5948.1000270